en
Scientific article
Letter
English

The hydroalumination of ω-terbutoxy alkynes an easy access to ω-hydroxy alkenyl iodides. Application to the synthesis of dienic insect pheromone

Published inTetrahedron letters, vol. 29, no. 48, p. 6243-6246
Publication date1988
Abstract

In contrast to classically protected ω-hydroxy alkynes, ω-terbutoxy alkynes undergo smooth hydroalumination with DIBAL-H. The obtained E or Z alkenyl alanes are iodinated leading to E or Z alkenyl iodides. The ω-terbutoxy group is easily converted into an acetate. The latter compounds are useful synthons for the synthesis of insect pheromones as examplified with two cases.

Affiliation Not a UNIGE publication
Citation (ISO format)
ALEXAKIS, Alexandre, DUFFAULT, Jean-Marc. The hydroalumination of ω-terbutoxy alkynes an easy access to ω-hydroxy alkenyl iodides. Application to the synthesis of dienic insect pheromone. In: Tetrahedron letters, 1988, vol. 29, n° 48, p. 6243–6246. doi: 10.1016/S0040-4039(00)82315-1
Identifiers
ISSN of the journal0040-4039
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