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Scientific article
English

Enantioselective ortho-lithiation of benzaldehyde chromiumtricarbonyl complex

Published inTetrahedron: asymmetry, vol. 6, no. 9, p. 2135-2138
Publication date1995
Abstract

The asymmetric ortho lithiation of benzaldehyde chromiumtricarbonyl complex is performed by in situ temporary protection of the aldehyde functionality with a chiral amide and BuLi as metallating agent. Reaction with an electrophile followed by acidic hydrolysis leads to the enantiomerically enriched ortho substituted benzaldehyde chromiumtricarbonyl complex.

Affiliation Not a UNIGE publication
Citation (ISO format)
ALEXAKIS, Alexandre et al. Enantioselective ortho-lithiation of benzaldehyde chromiumtricarbonyl complex. In: Tetrahedron: asymmetry, 1995, vol. 6, n° 9, p. 2135–2138. doi: 10.1016/0957-4166(95)00283-U
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ISSN of the journal0957-4166
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