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Title

Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases

Authors
Tierney, Jason P.
Mangeney, Pierre
Published in Tetrahedron: Asymmetry. 1997, vol. 8, no. 7, p. 1019-1022
Abstract (R)-2-Cyclohexen-1-ol and (R)-2-cyclooctene-1-ol have been prepared in very good ee using R,R-homochiral bis-lithium amide bases derived from homochiral C2 symmetric diamines. (R)-2-Cyclohexen-1-ol has been synthesized in good ee utilising catalytic homochiral bis-lithium amide in the presence of n-butyl lithium.
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TIERNEY, Jason P., ALEXAKIS, Alexandre, MANGENEY, Pierre. Catalytic enantioselective deprotonation of meso-epoxides utilising homochiral bis-lithium amide bases. In: Tetrahedron: Asymmetry, 1997, vol. 8, n° 7, p. 1019-1022. https://archive-ouverte.unige.ch/unige:8060

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Deposited on : 2010-06-21

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