Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents

Alexakis, Alexandre; Mhamdi, Farida; Lagasse, Franz; Mangeney, Pierre

doi:10.1016/S0957-4166(96)00438-7

Scientific article

English

Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents

ContributorsAlexakis, Alexandre; Mhamdi, Farida; Lagasse, Franz; Mangeney, Pierre

Published inTetrahedron: asymmetry, vol. 7, no. 12, p. 3343-3346

Publication date1996

Abstract

a,ß-Ethylenic chiral acetals react regio- and stereoselectively with organolithium reagents. The obtained enol ether may be hydrolyzed into a chiral ß-disubstituted aldehyde.

Affiliation entities

Not a UNIGE publication

Citation (ISO format)

ALEXAKIS, Alexandre et al. Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents. In: Tetrahedron: asymmetry, 1996, vol. 7, n° 12, p. 3343–3346. doi: 10.1016/S0957-4166(96)00438-7

Article (Published version)

Identifiers

PID : unige:8057
DOI : 10.1016/S0957-4166(96)00438-7

Journal ISSN0957-4166

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Creation21/06/2010 16:15:56

First validation21/06/2010 16:15:56

Update time14/03/2023 16:47:53

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Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents

a,ß-Ethylenic chiral acetals react regio- and stereoselectively with organolithium reagents. The obtained enol ether may be hydrolyzed into a chiral ß-disubstituted aldehyde.

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