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Enantioselective catalytic rearrangement of cyclohexene oxide with new homochiral bis-lithium amide bases

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Published in Tetrahedron: Asymmetry. 2004, vol. 15, no. 7, p. 1069-1072
Abstract Cyclohexene oxide can be rearranged with good levels of induction (up to 68% ee) with substoichiometric amounts of chiral bases derived from readily available diamines. The influence of the steric bulk of the amine substituents on the rearrangement enantioselectivity has also been studied.
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EQUEY, Olivier, ALEXAKIS, Alexandre. Enantioselective catalytic rearrangement of cyclohexene oxide with new homochiral bis-lithium amide bases. In: Tetrahedron: Asymmetry, 2004, vol. 15, n° 7, p. 1069-1072. https://archive-ouverte.unige.ch/unige:8056

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Deposited on : 2010-06-21

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