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Title

Enantioselective copper-catalyzed conjugate addition using chiral diaminocarbene ligands
Authors
Guillen, Frédéric
Winn, Caroline Louise
Alexakis, Alexandre
Published in Tetrahedron: Asymmetry. 2001, vol. 12, no. 15, p. 2083-2086
Abstract Chiral diaminocarbene ligands, generated by in-situ deprotonation of the corresponding chiral imidazolinium salts, are shown to be efficient ligands in the asymmetric copper-catalyzed 1,4-conjugate addition of diethylzinc to enones, allowing enantiomeric excesses of up to 51% to be achieved.
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Article (Published version) - document accessible for UNIGE members only Limited access to UNIGE
Structures
Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation
(ISO format) 		GUILLEN, Frédéric, WINN, Caroline Louise, ALEXAKIS, Alexandre. Enantioselective copper-catalyzed conjugate addition using chiral diaminocarbene ligands. In: Tetrahedron: Asymmetry, 2001, vol. 12, n° 15, p. 2083-2086. https://archive-ouverte.unige.ch/unige:8050

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Deposited on : 2010-06-21

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