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A highly effective phosphoramidite ligand for asymmetric allylic substitution

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Published in Angewandte Chemie: International Edition. 2004, vol. 43, no. 18, p. 2426-2428
Abstract Very high enantioselectivity has been achieved both in the copper-catalyzed alkylation of allylic substrates by Grignard and organozinc reagents and in the iridium-catalyzed amination of cinnamyl carbonate by employing a very efficient phosphoramidite ligand
Keywords AllylationAsymmetric catalysisChiral auxiliariesCopperIridiumMagnesium
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TISSOT-CROSET, Karine, POLET, Damien, ALEXAKIS, Alexandre. A highly effective phosphoramidite ligand for asymmetric allylic substitution. In: Angewandte Chemie: International Edition, 2004, vol. 43, n° 18, p. 2426-2428. https://archive-ouverte.unige.ch/unige:8048

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Deposited on : 2010-06-21

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