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Scientific Article - Letter
unige:8042 
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First organocatalyzed asymmetric Michael addition of aldehydes to vinyl sufones |
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| Authors | ||
| Published in | Organic Letters. 2005, vol. 7, no. 20, p. 4361-4364 | |
| Abstract | The first asymmetric direct Michael addition of aldehydes to vinyl sulfones catalyzed by N-iPr-2,2'-bipyrrolidine is described. 1,4-Adducts are obtained in good yields and enantioselectivities. The determination of absolute configuration allowed us to postulate a Si,Si transition state model, as shown previously for nitroolefins. | |
| Identifiers | DOI: 10.1021/ol051488h PMID: 16178533 | |
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| Citation (ISO format) | SULZER MOSSÉ, Sarah, ALEXAKIS, Alexandre. First organocatalyzed asymmetric Michael addition of aldehydes to vinyl sufones. In: Organic Letters, 2005, vol. 7, n° 20, p. 4361-4364. https://archive-ouverte.unige.ch/unige:8042 |
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