First organocatalyzed asymmetric Michael addition of aldehydes to vinyl sufones

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Title		First organocatalyzed asymmetric Michael addition of aldehydes to vinyl sufones
Authors		Sulzer Mossé, Sarah Alexakis, Alexandre
Published in		Organic Letters. 2005, vol. 7, no. 20, p. 4361-4364
Abstract		The first asymmetric direct Michael addition of aldehydes to vinyl sulfones catalyzed by N-iPr-2,2'-bipyrrolidine is described. 1,4-Adducts are obtained in good yields and enantioselectivities. The determination of absolute configuration allowed us to postulate a Si,Si transition state model, as shown previously for nitroolefins.
Identifiers		DOI: 10.1021/ol051488h PMID: 16178533
Full text		Article (Published version) - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		SULZER MOSSÉ, Sarah, ALEXAKIS, Alexandre. First organocatalyzed asymmetric Michael addition of aldehydes to vinyl sufones. In: Organic Letters, 2005, vol. 7, n° 20, p. 4361-4364. doi: 10.1021/ol051488h https://archive-ouverte.unige.ch/unige:8042