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Title

First organocatalyzed asymmetric Michael addition of aldehydes to vinyl sufones
Authors
Sulzer Mosse, Sarah
Alexakis, Alexandre
Published in Organic Letters. 2005, vol. 7, no. 20, p. 4361-4364
Abstract The first asymmetric direct Michael addition of aldehydes to vinyl sulfones catalyzed by N-iPr-2,2'-bipyrrolidine is described. 1,4-Adducts are obtained in good yields and enantioselectivities. The determination of absolute configuration allowed us to postulate a Si,Si transition state model, as shown previously for nitroolefins.
Identifiers
PMID: 16178533
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Article (Published version) - document accessible for UNIGE members only Limited access to UNIGE
Structures
Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation
(ISO format) 		SULZER MOSSE, Sarah, ALEXAKIS, Alexandre. First organocatalyzed asymmetric Michael addition of aldehydes to vinyl sufones. In: Organic Letters, 2005, vol. 7, n° 20, p. 4361-4364. https://archive-ouverte.unige.ch/unige:8042

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Deposited on : 2010-06-21

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