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Very efficient phosphoramidite ligand for asymmetric iridium-catalyzed allylic alkylation

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Published in Organic Letters. 2004, vol. 6, no. 20, p. 3529-3552
Abstract Linear or branched allylic carbonates or acetates undergo enantioselective iridium-catalyzed allylic substitution with sodium malonate. The reaction is wide in scope and affords the branched product in high yield and with high regio- (up to >99:1) and enantioselectivity (up to 98%). Ten aromatic or aliphatic substrates were successfully tested.
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PMID: 15387540
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ALEXAKIS, Alexandre, POLET, Damien. Very efficient phosphoramidite ligand for asymmetric iridium-catalyzed allylic alkylation. In: Organic Letters, 2004, vol. 6, n° 20, p. 3529-3552. https://archive-ouverte.unige.ch/unige:8041

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Deposited on : 2010-06-21

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