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Enantioselective copper-catalyzed conjugate addition of dialkylzinc to nitro-olefins

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Published in Organic Letters. 2000, vol. 2, no. 17, p. 2579-2581
Abstract The copper-catalyzed asymmetric conjugate addition of dialkylzinc onto various nitro-olefins has been carried out with excellent results. An enantiomeric excess of up to 94% was obtained using 0.5% Cu(OTf)2 and 1% of chiral trivalent phosphorus ligand.
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ALEXAKIS, Alexandre, BENHAIM, Cyril. Enantioselective copper-catalyzed conjugate addition of dialkylzinc to nitro-olefins. In: Organic Letters, 2000, vol. 2, n° 17, p. 2579-2581. https://archive-ouverte.unige.ch/unige:8035

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Deposited on : 2010-06-21

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