en
Scientific article
English

Remote Asymmetric Induction. New Mechanistic Insights Concerning the SN‘ and SN‘‘ Substitution in Organocopper Chemistry

Published inOrganometallics, vol. 15, no. 8, p. 1957-1959
Publication date1996
Abstract

The addition of the PhCu, BF3.Et2O reagent to chiral dienic acetals was studied. The regioselectivity of the reaction was found to be dependent on the nature of the starting acetal. More importantly, the stereochemistry of the SN2'' reaction was found to be opposite to the one observed for the SN2' reaction. Acidic hydrolysis of the resulting enol ethers afforded the corresponding chiral ä-substituted aldehydes.

Affiliation Not a UNIGE publication
Citation (ISO format)
RAKOTOARISOA, Haja et al. Remote Asymmetric Induction. New Mechanistic Insights Concerning the SN‘ and SN‘‘ Substitution in Organocopper Chemistry. In: Organometallics, 1996, vol. 15, n° 8, p. 1957–1959. doi: 10.1021/om950921w
Main files (1)
Article (Published version)
accessLevelRestricted
Identifiers
ISSN of the journal0276-7333
552views
0downloads

Technical informations

Creation06/21/2010 2:15:43 PM
First validation06/21/2010 2:15:43 PM
Update time03/14/2023 3:47:46 PM
Status update03/14/2023 3:47:46 PM
Last indexation01/15/2024 8:25:56 PM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack