Iridium-Catalysed asymmetric allylic substitution with aryl zinc reaggents

Alexakis, Alexandre; El Hajjaji, Samir; Polet, Damien; Rathgeb, Xavier

doi:10.1021/ol0713842

Scientific article

English

Iridium-Catalysed asymmetric allylic substitution with aryl zinc reaggents

ContributorsAlexakis, Alexandre; El Hajjaji, Samir; Polet, Damien; Rathgeb, Xavier

Published inOrganic letters, vol. 9, no. 17, p. 3393-3395

Publication date2007

Abstract

Thanks to iridium catalysis, arylzinc reagents undergo regioselective allylic substitution with very high enantioselectivity, when associated with phosphoramidite ligands.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

ALEXAKIS, Alexandre et al. Iridium-Catalysed asymmetric allylic substitution with aryl zinc reaggents. In: Organic letters, 2007, vol. 9, n° 17, p. 3393–3395. doi: 10.1021/ol0713842

Article (Published version)

Identifiers

PID : unige:8024
DOI : 10.1021/ol0713842
PMID : 17637062

Journal ISSN1523-7052

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Iridium-Catalysed asymmetric allylic substitution with aryl zinc reaggents

Thanks to iridium catalysis, arylzinc reagents undergo regioselective allylic substitution with very high enantioselectivity, when associated with phosphoramidite ligands.

Technical informations