Chiral amines as organocatalysts for asymmetric conjugate addition to nitroolefins and vinyl sulfones via enamine activation

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Title		Chiral amines as organocatalysts for asymmetric conjugate addition to nitroolefins and vinyl sulfones via enamine activation
Authors		Sulzer Mossé, Sarah Alexakis, Alexandre
Published in		Chemical Communications. 2007, no. 30, p. 3123-3135
Abstract		Over the last decade the potential of organocatalysis has successfully been demonstrated. In particular, chiral amines such as pyrrolidine analogues have emerged as a broadly applicable class of organocatalyst for asymmetric conjugate addition via enamine activation. This Feature Article documents the development of these catalysts, emphasizing the design and mechanistic features that supply high selectivity in asymmetric Michael reactions.
Identifiers		DOI: 10.1039/b701216k PMID: 17653365
Full text		Article (Published version) - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		SULZER MOSSÉ, Sarah, ALEXAKIS, Alexandre. Chiral amines as organocatalysts for asymmetric conjugate addition to nitroolefins and vinyl sulfones via enamine activation. In: Chemical Communications, 2007, n° 30, p. 3123-3135. doi: 10.1039/b701216k https://archive-ouverte.unige.ch/unige:8018