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Title

β-Disubstituted Allylic Chloride: Substrate for th Cu-Catalyzed Asymmetric SN2' Reaction

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Published in Angewandte Chemie: International Edition. 2006, vol. 45, no. 36, p. 5995-5998
Abstract Scope broadened: A previously developed asymmetric Cu-catalyzed allylic substitution can be applied to more substituted allylic patterns. Two classes of -disubstituted substrates, cinnamyl derivatives and aliphatic endocyclic allylic chlorides, afford excellent regio- and enantioselectivities (see schemes; L*=phosphoramidite ligand).
Keywords AlkylationAllylic compoundsAsymmetric catalysisCopperNucleophilic substitution
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PMID: 16888831
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FALCIOLA, Caroline Alexandra, TISSOT-CROSET, Karine, ALEXAKIS, Alexandre. β-Disubstituted Allylic Chloride: Substrate for th Cu-Catalyzed Asymmetric SN2' Reaction. In: Angewandte Chemie: International Edition, 2006, vol. 45, n° 36, p. 5995-5998. https://archive-ouverte.unige.ch/unige:8014

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Deposited on : 2010-06-21

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