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Asymmetric Lewis Acid-Catalyzed 1,3-Dipolar Cycloadditions

Badoui, Andrei
Published in Pure and Applied Chemistry. 2008, vol. 80, no. 5, p. 1013-1018
Abstract Highly tuned, one-point binding chiral iron and ruthenium complexes selectively coordinate and activate α,β-unsaturated aldehydes and ketones toward asymmetric catalytic Diels-Alder cycloaddition reactions. Here we focus on the application of these transition-metal Lewis acids to asymmetric catalytic 1,3-dipolar cycloaddition reaction between enals and cyclic and acyclic nitrones as well as aryl nitrile oxides to give isoxazolidines and isoxazolines, respectively.
Keywords 1,3-dipolar cycloadditionsAsymmetric reactionsLewis acidsNitrile oxidesNitrones
Note 14th International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS-14). - Nara (Japan). - 2–6 August 2007
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BADOUI, Andrei et al. Asymmetric Lewis Acid-Catalyzed 1,3-Dipolar Cycloadditions. In: Pure and Applied Chemistry, 2008, vol. 80, n° 5, p. 1013-1018. https://archive-ouverte.unige.ch/unige:8006

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Deposited on : 2010-06-21

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