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Scientific article
Letter
English

Synthesis of a Bicyclo[8.3.1]enediyne via Chromium-Mediated Dearomatization of 2,6-Bis(trimethylsilyl)anisole

Published inSynlett, no. 17, p. 2621-2624
Publication date2008
Abstract

A novel bicyclo[8.3.1]enediyne was readily synthesized by chromium-mediated dearomatization of 2,6-bis(trimethyl­silyl)anisole. The enediyne undergoes Bergman cyclization with a half-life of 14.4 hours at 142 °C.

Keywords
  • Enediynes
  • Dearomatization
  • [Cr(arene)(CO)3] complexes
  • Bergman cyclization
  • Nicholas reaction
Citation (ISO format)
LAVY, Severine, PÉREZ-LUNA, Alejandro, KUNDIG, Ernst Peter. Synthesis of a Bicyclo[8.3.1]enediyne via Chromium-Mediated Dearomatization of 2,6-Bis(trimethylsilyl)anisole. In: Synlett, 2008, n° 17, p. 2621–2624. doi: 10.1055/s-0028-1083513
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ISSN of the journal0936-5214
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Creation06/21/2010 10:31:03 AM
First validation06/21/2010 10:31:03 AM
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