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Title

Synthesis of a Bicyclo[8.3.1]enediyne via Chromium-Mediated Dearomatization of 2,6-Bis(trimethylsilyl)anisole

Authors
Pérez-Luna, Alejandro
Published in Synlett. 2008, no. 17, p. 2621-2624
Abstract A novel bicyclo[8.3.1]enediyne was readily synthesized by chromium-mediated dearomatization of 2,6-bis(trimethyl­silyl)anisole. The enediyne undergoes Bergman cyclization with a half-life of 14.4 hours at 142 °C.
Keywords EnediynesDearomatization[Cr(arene)(CO)3] complexesBergman cyclizationNicholas reaction
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LAVY, Severine, PÉREZ-LUNA, Alejandro, KUNDIG, Ernst Peter. Synthesis of a Bicyclo[8.3.1]enediyne via Chromium-Mediated Dearomatization of 2,6-Bis(trimethylsilyl)anisole. In: Synlett, 2008, n° 17, p. 2621-2624. https://archive-ouverte.unige.ch/unige:7961

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Deposited on : 2010-06-21

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