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Lewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates

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Published in Organic and Biomolecular Chemistry. 2009, vol. 7, no. 19, p. 4057-4061
Abstract The addition of a Lewis acidic metal triflate salt Mg(OTf)(2) as co-catalyst in the CpRu-catalyzed decarboxylative allylation of in situ-generated ketone enolates allows the reaction to proceed at lower temperature with higher regio- and enantioselectivity. Even so-far-unreactive substrates react.
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PMID: 19763311
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LINDER, David, AUSTERI, Martina, LACOUR, Jérôme. Lewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates. In: Organic and Biomolecular Chemistry, 2009, vol. 7, n° 19, p. 4057-4061. https://archive-ouverte.unige.ch/unige:7960

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Deposited on : 2010-06-21

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