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Title

Lewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates
Authors
Linder, David
Austeri, Martina
Lacour, Jérôme
Published in Organic and Biomolecular Chemistry. 2009, vol. 7, no. 19, p. 4057-4061
Abstract The addition of a Lewis acidic metal triflate salt Mg(OTf)(2) as co-catalyst in the CpRu-catalyzed decarboxylative allylation of in situ-generated ketone enolates allows the reaction to proceed at lower temperature with higher regio- and enantioselectivity. Even so-far-unreactive substrates react.
Identifiers
PMID: 19763311
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Article - document accessible for UNIGE members only Limited access to UNIGE
Structures
Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation
(ISO format) 		LINDER, David, AUSTERI, Martina, LACOUR, Jérôme. Lewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates. In: Organic and Biomolecular Chemistry, 2009, vol. 7, n° 19, p. 4057-4061. https://archive-ouverte.unige.ch/unige:7960

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Deposited on : 2010-06-21

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