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Titles listLewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates
Titles listLewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates
Scientific Article
unige:7960 
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Lewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates |
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| Published in | Organic and Biomolecular Chemistry. 2009, vol. 7, no. 19, p. 4057-4061 | |
| Abstract | The addition of a Lewis acidic metal triflate salt Mg(OTf)(2) as co-catalyst in the CpRu-catalyzed decarboxylative allylation of in situ-generated ketone enolates allows the reaction to proceed at lower temperature with higher regio- and enantioselectivity. Even so-far-unreactive substrates react. | |
| Identifiers | DOI: 10.1039/b910475e PMID: 19763311 | |
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| Citation (ISO format) | LINDER, David, AUSTERI, Martina, LACOUR, Jérôme. Lewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates. In: Organic and Biomolecular Chemistry, 2009, vol. 7, n° 19, p. 4057-4061. doi: 10.1039/b910475e https://archive-ouverte.unige.ch/unige:7960 |
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