en
Scientific article
English

Lewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates

Published inOrganic & biomolecular chemistry, vol. 7, no. 19, p. 4057-4061
Publication date2009
Abstract

The addition of a Lewis acidic metal triflate salt Mg(OTf)(2) as co-catalyst in the CpRu-catalyzed decarboxylative allylation of in situ-generated ketone enolates allows the reaction to proceed at lower temperature with higher regio- and enantioselectivity. Even so-far-unreactive substrates react.

Citation (ISO format)
LINDER, David, AUSTERI, Martina, LACOUR, Jérôme. Lewis acid/CpRu dual catalysis in the enantioselective decarboxylative allylation of ketone enolates. In: Organic & biomolecular chemistry, 2009, vol. 7, n° 19, p. 4057–4061. doi: 10.1039/b910475e
Main files (1)
Article
accessLevelRestricted
Identifiers
ISSN of the journal1477-0520
553views
0downloads

Technical informations

Creation06/21/2010 10:31:01 AM
First validation06/21/2010 10:31:01 AM
Update time03/14/2023 3:47:27 PM
Status update03/14/2023 3:47:27 PM
Last indexation02/12/2024 6:45:42 PM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack