Synthesis and Structure of a Trimeric Cyclometalated Coordination Compound with a Hydrophobic Cavity

Ruttimann, Stéphane Joséph; Williams, Alan Francis; Bernardinelli, Gérald Hugues

doi:10.1002/anie.199303921

Scientific article

English

Synthesis and Structure of a Trimeric Cyclometalated Coordination Compound with a Hydrophobic Cavity

ContributorsRuttimann, Stéphane Joséph; Williams, Alan Francis; Bernardinelli, Gérald Hugues

Published inAngewandte Chemie, vol. 32, no. 3, p. 392-394

Publication date1993

Abstract

A molecular tricorn is the best description of complex 2, which arises from ligand 1 and palladium(II) acetate by cyclopalladation and trimerization. Since 2 has a hydrophobic cavity, it may serve as a host for neutral guest molecules, such as acetonitrile. • = Pd.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie minérale, analytique et appliquée

Citation (ISO format)

RUTTIMANN, Stéphane Joséph, WILLIAMS, Alan Francis, BERNARDINELLI, Gérald Hugues. Synthesis and Structure of a Trimeric Cyclometalated Coordination Compound with a Hydrophobic Cavity. In: Angewandte Chemie, 1993, vol. 32, n° 3, p. 392–394. doi: 10.1002/anie.199303921

Article (Published version)

Identifiers

PID : unige:79462
DOI : 10.1002/anie.199303921

Journal ISSN1433-7851

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Synthesis and Structure of a Trimeric Cyclometalated Coordination Compound with a Hydrophobic Cavity

A molecular tricorn is the best description of complex 2, which arises from ligand 1 and palladium(II) acetate by cyclopalladation and trimerization. Since 2 has a hydrophobic cavity, it may serve as a host for neutral guest molecules, such as acetonitrile. • = Pd.

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