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Structure of a One-Dimensional Infinite Double-Helical Copper(I) Complex

Published in Angewandte Chemie. 1993, vol. 32, no. 10, p. 1463-1465
Abstract Not intra-, but intermolecular stacking interactions between imidazole rings are responsible for the self assembly of the ainuclear Cu1 complex [Cu2L2]2+ to an infinite double-helical polymer (picture on the right) in the solid state. In recent years a range of double-helical complexes of low-molecular weight has been prepared; however, [Cu2L2]math image is the first polymeric complex of this type.
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CARINA, Riccardo, BERNARDINELLI, Gérald Hugues, WILLIAMS, Alan Francis. Structure of a One-Dimensional Infinite Double-Helical Copper(I) Complex. In: Angewandte Chemie: International Edition, 1993, vol. 32, n° 10, p. 1463-1465. doi: 10.1002/anie.199314631 https://archive-ouverte.unige.ch/unige:79461

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