Synthesis of Spiro Ketals, Orthoesters, and Orthocarbonates by CpRu-Catalyzed Decomposition of α-Diazo-β-ketoesters

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Title		Synthesis of Spiro Ketals, Orthoesters, and Orthocarbonates by CpRu-Catalyzed Decomposition of α-Diazo-β-ketoesters
Authors		Tortoreto, Cecilia Achard, Thierry Egger, Leo Guenee, Laure Lacour, Jérôme
Published in		Organic Letters. 2016, vol. 18, no. 3, p. 240-243
Abstract		Reactions of α-diazo-β-ketoesters with cyclic ketones, lactones, and carbonates are reported. Thanks to the combined use of salt [CpRu(CH3CN)3][BArF] and 1,10-phenanthroline as catalyst for the diazo decomposition, effective and practical syntheses of spiro bicyclic ketals, orthoesters, and orthocarbonates are afforded.
Identifiers		DOI: 10.1021/acs.orglett.5b03380
Full text		Article (Published version) (1 MB) - Limited access to UNIGE Other version: http://pubs.acs.org/doi/10.1021/acs.orglett.5b03380
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Research group		Groupe Lacour
Citation (ISO format)		TORTORETO, Cecilia et al. Synthesis of Spiro Ketals, Orthoesters, and Orthocarbonates by CpRu-Catalyzed Decomposition of α-Diazo-β-ketoesters. In: Organic Letters, 2016, vol. 18, n° 3, p. 240-243. https://archive-ouverte.unige.ch/unige:79450

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Deposited on : 2016-01-18

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