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Scientific article
English

Synthesis of Spiro Ketals, Orthoesters, and Orthocarbonates by CpRu-Catalyzed Decomposition of α-Diazo-β-ketoesters

Published inOrganic letters, vol. 18, no. 3, p. 240-243
Publication date2016
Abstract

Reactions of α-diazo-β-ketoesters with cyclic ketones, lactones, and carbonates are reported. Thanks to the combined use of salt [CpRu(CH3CN)3][BArF] and 1,10-phenanthroline as catalyst for the diazo decomposition, effective and practical syntheses of spiro bicyclic ketals, orthoesters, and orthocarbonates are afforded.

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Citation (ISO format)
TORTORETO, Cecilia et al. Synthesis of Spiro Ketals, Orthoesters, and Orthocarbonates by CpRu-Catalyzed Decomposition of α-Diazo-β-ketoesters. In: Organic letters, 2016, vol. 18, n° 3, p. 240–243. doi: 10.1021/acs.orglett.5b03380
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ISSN of the journal1523-7052
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Creation01/15/2016 9:34:00 AM
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