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Scientific article
English

Iridium-catalyzed Isomerization of Primary Allylic Alcohols

Published inChimia, vol. 63, no. 1-2, p. 35-37
Publication date2009
Abstract

A readily accessible iridium hydrogenation catalyst displays high reactivity for the isomerization of primary allylic alcohols under mild reaction conditions. Key to the efficiency of the catalytic system is to deviate from the conventional hydrogenation route in favor of the desired isomerization pathway by adequately tuning the reaction conditions as indicated by preliminary mechanistic investigations.

Keywords
  • Allylic alcohols
  • Homogeneous catalysis
  • Iridium
  • Isomerization
Citation (ISO format)
MANTILLI, Luca, MAZET, Clement. Iridium-catalyzed Isomerization of Primary Allylic Alcohols. In: Chimia, 2009, vol. 63, n° 1-2, p. 35–37. doi: 10.2533/chimia.2009.35
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ISSN of the journal0009-4293
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Technical informations

Creation06/21/2010 10:28:50 AM
First validation06/21/2010 10:28:50 AM
Update time03/14/2023 3:47:23 PM
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