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Scientific article
English

Iridium-catalyzed asymmetric isomerization of primary allylic alcohols

Published inAngewandte Chemie, vol. 48, no. 28, p. 5143-5147
Publication date2009
Abstract

Nothing to sm(Ir)k at: Under appropriate reaction conditions, iridium hydride catalysts promote the isomerization of primary allylic alcohols. The best catalysts, like (R)-1 (P green, O red, N blue, Ir yellow), deliver the desired chiral aldehydes with excellent enantioselectivity and good yields. Mechanistic hypotheses have been developed on the basis of preliminary investigations.

Citation (ISO format)
MANTILLI, Luca et al. Iridium-catalyzed asymmetric isomerization of primary allylic alcohols. In: Angewandte Chemie, 2009, vol. 48, n° 28, p. 5143–5147. doi: 10.1002/anie.200901863
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