Scientific article
English

First-Order Phase Transition to Strongly Anisotropic Ferromagnetism in Tl2Mo6Te6

Published inJournal of magnetism and magnetic materials, vol. 42, no. 1, no. PHYP73, p. 167-172
Publication date1984
Abstract

The magnetic susceptibility, magnetization, specific heat and electrical resistivity were measured on the new material Tl2Fe6Te6. All the data show a very sharp anomaly revealing a phase transition to ferromagnetism at Tc ≈ 220 K. The presence in the structure of one-dimensional metallic cluster ¦Fe3¦1∞ is evidenced by a very strong magnetic anisotropy in the ferromagnetic state, showing an interesting intermediate situation between a pure linear chain and 3-dimensional iron. Furthermore, the unusual sharpness of the transition leads us to anticipate a first-order phase transformation, but the lack of detectable thermal hysteresis was surprising. The molecular field model proposed by Bean and Rodbell in order to account for the similar behaviour of MnAs gives a close representation of our magnetic data. Thus, a pronounced dependence of the exchange interaction upon interatomic spacing may well be the dominant mechanism leading to the observed phenomena.

Citation (ISO format)
PELIZZONE, Marco et al. First-Order Phase Transition to Strongly Anisotropic Ferromagnetism in Tl2Mo6Te6. In: Journal of magnetism and magnetic materials, 1984, vol. 42, n° 1, p. 167–172. doi: 10.1016/0304-8853(84)90306-8
Main files (1)
Article (Published version)
accessLevelRestricted
Identifiers
Journal ISSN0304-8853
434views
1downloads

Technical informations

Creation13/01/2016 08:29:00
First validation13/01/2016 08:29:00
Update23/01/2026 08:51:21
Status update23/01/2026 08:51:21
Last indexation23/01/2026 08:51:22
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack