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Scientific article
English

Determination of Coupling Constants by Deconvolution of Multiplets in NMR

Published inJournal of magnetic resonance, vol. 141, no. 1, p. 133-140
Publication date1999
Abstract

The structures of multiplets in one- and two-dimensional NMR spectra can be simplified by recursive deconvolution in the frequency domain. Deconvolution procedures are described for in-phase and antiphase doublets of delta functions. Recursive simplification is illustrated by applications to double-quantum-filtered correlation spectra (DQF-COSY) and selective correlation spectra (soft-COSY). Coupling constants can be measured reliably even if signals of opposite signs lead to partial cancellation.

Keywords
  • Deconvolution of multiplets
  • Correlation spectroscopy (COSY)
  • Cross-peak multiplets
Citation (ISO format)
JEANNERAT, Damien, BODENHAUSEN, Geoffrey. Determination of Coupling Constants by Deconvolution of Multiplets in NMR. In: Journal of magnetic resonance, 1999, vol. 141, n° 1, p. 133–140. doi: 10.1006/jmre.1999.1845
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ISSN of the journal1090-7807
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