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Title

Thermodynamically Preferred Axial Allylic -NHTs Substituent in Simple 1-Triisopropylsilyl(oxy) Cyclohexenes: Solid State Conformation by X-ray Crystallography

Authors
Magnus, Philip
Bauta, William
Mugrage, Benjamin
Lynch, Vincent
Published in Journal of the Chemical Society. Chemical Communications. 1991, no. 19, p. 1362-1364
Abstract For a series of 6-(4-methylphenylsulphonyl)amino-1-triisopropylsilyl(oxy)-cyclohexenes the preferred conformation, in the solid state, has the –NHTs (Ts = 4-methylphenylsulphonyl) group in an axial orientation; if the axial-NHTs group experiences a 1,3-diaxial interaction with a methyl group, the equatorial conformation becomes the thermodynamically more stable form.
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MAGNUS, Philip et al. Thermodynamically Preferred Axial Allylic -NHTs Substituent in Simple 1-Triisopropylsilyl(oxy) Cyclohexenes: Solid State Conformation by X-ray Crystallography. In: Journal of the Chemical Society. Chemical Communications, 1991, n° 19, p. 1362-1364. https://archive-ouverte.unige.ch/unige:7923

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Deposited on : 2010-06-21

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