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Enantioselective gas chromatographic analysis of cyclopropane derivatives

Aboul-Enein, Hassan Y.
Jiang, Z.
Published in Chromatographia. 2005, vol. 61, no. 3-4, p. 103-111
Abstract Chirasil-beta-Dex was used as chiral stationary phase for the enantioselective gas chromatographic analysis of several new chiral cyclopropane derivatives. The GC method provides information about the chemical yields of the cyclopropane products, enantioselectivity, substrate specifity, and catalytic activity of the chiral catalysts used in the inter- and intra-molecular cyclopropanation reactions and avoids time-consuming work-up procedures.
Keywords Gas chromatographyEnantiomeric excessChirasil-beta-DexRhodium complexesCyclopropanes
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GHANEM ABDALLAH, Ashraf et al. Enantioselective gas chromatographic analysis of cyclopropane derivatives. In: Chromatographia, 2005, vol. 61, n° 3-4, p. 103-111. https://archive-ouverte.unige.ch/unige:7913

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Deposited on : 2010-06-21

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