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Scientific article
Open access
English

Enantioselective gas chromatographic analysis of cyclopropane derivatives

Published inChromatographia, vol. 61, no. 3-4, p. 103-111
Collection
  • Open Access - Licence nationale Springer
Publication date2005
Abstract

Chirasil-beta-Dex was used as chiral stationary phase for the enantioselective gas chromatographic analysis of several new chiral cyclopropane derivatives. The GC method provides information about the chemical yields of the cyclopropane products, enantioselectivity, substrate specifity, and catalytic activity of the chiral catalysts used in the inter- and intra-molecular cyclopropanation reactions and avoids time-consuming work-up procedures.

Keywords
  • Gas chromatography
  • Enantiomeric excess
  • Chirasil-beta-Dex
  • Rhodium complexes
  • Cyclopropanes
Citation (ISO format)
GHANEM ABDALLAH, Ashraf et al. Enantioselective gas chromatographic analysis of cyclopropane derivatives. In: Chromatographia, 2005, vol. 61, n° 3-4, p. 103–111. doi: 10.1365/s10337-004-0425-3
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Article (Published version)
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Identifiers
ISSN of the journal0009-5893
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