Dicarbonylbis(1,4-difluoro-2,3,5,6-tetramethyl-1,4-diboracyclohexa-2,5-diene)molybdenum

Anderson, Kirsty M.; Kundig, Ernst Peter; Norman, Nicholas C.; Orpen, A. Guy; Pardoe, Jennifer A.J.; Smith, David W.; Timms, Peter L.

doi:10.1107/S1600536801014167

Scientific article

English

Dicarbonylbis(1,4-difluoro-2,3,5,6-tetramethyl-1,4-diboracyclohexa-2,5-diene)molybdenum

ContributorsAnderson, Kirsty M.; Kundig, Ernst Peter; Norman, Nicholas C.; Orpen, A. Guy; Pardoe, Jennifer A.J.; Smith, David W.; Timms, Peter L.

Published inActa crystallographica. Section E, vol. 57, no. 10, p. m419-m420

Publication date2001

Abstract

The structure of the title compound, [Mo(?6-C4Me4B2F2)2(CO)2], (II), was determined by X-ray crystallography at 173 K and has two independent molecules of (II) in the asymmetric unit. The six-membered diboracycles are ?6-coordinated [Mo—Calkene = 2.4157 (18)–2.6008 (19); Mo—B = 2.538 (2)–2.621 (2) Å].

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

ANDERSON, Kirsty M. et al. Dicarbonylbis(1,4-difluoro-2,3,5,6-tetramethyl-1,4-diboracyclohexa-2,5-diene)molybdenum. In: Acta crystallographica. Section E, 2001, vol. 57, n° 10, p. m419–m420. doi: 10.1107/S1600536801014167

Article

Identifiers

PID : unige:7906
DOI : 10.1107/S1600536801014167

ISSN of the journal1600-5368

500views

1downloads

Creation06/21/2010 10:28:30 AM

First validation06/21/2010 10:28:30 AM

Update time03/14/2023 3:47:13 PM

Status update03/14/2023 3:47:13 PM

Last indexation02/12/2024 6:44:35 PM

Archive ouverte UNIGE

Dicarbonylbis(1,4-difluoro-2,3,5,6-tetramethyl-1,4-diboracyclohexa-2,5-diene)molybdenum

Technical informations