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Title

Efficient Synthesis of Tris(acetonitrile)-(η5-cyclopentadienyl)-ruthenium(II) Hexafluorophosphate via Ruthenocene

Authors
Monnier, F.R.
Published in Advanced Synthesis and Catalysis. 2004, vol. 346, no. 8, p. 901-904
Abstract [Ru(η5-C5H5)(CH3CN)3][PF6] (1), a versatile precursor to catalysts containing the CpRu+ complex fragment, can be obtained in high yield via Cp/naphthalene exchange in ruthenocene. This new route via the complex [RuCp(naphthalene)][PF6] (4) avoids both highly toxic thallium reagents and the need for a photoreactor.
Keywords Arene complexesCyclopentadienyl ligandsLigand exchangeRutheniumRuthenocene
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Note Special Issue : Dedicated Cluster: Dedicated to Prof. Dr. J. Bargon on the occasion of his 65th birthday
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KUNDIG, Ernst Peter, MONNIER, F.R. Efficient Synthesis of Tris(acetonitrile)-(η5-cyclopentadienyl)-ruthenium(II) Hexafluorophosphate via Ruthenocene. In: Advanced Synthesis and Catalysis, 2004, vol. 346, n° 8, p. 901-904. https://archive-ouverte.unige.ch/unige:7887

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Deposited on : 2010-06-21

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