UNIGE document Scientific Article
previous document  unige:7886  next document
add to browser collection
Title

Chiral Cyclopentadienyl-Iron and -Ruthenium Lewis Acids Containing the Electron-Poor BIPHOP-F Ligand: a Comparison as Catalysts in an Asymmetric Diels-Alder Reaction

Authors
Saudan, C.M.
Published in Advanced Synthesis and Catalysis. 2001, vol. 343, no. 1, p. 51-56
Abstract Chiral iron and ruthenium Lewis acids: analogies and differences between the catalysts and the role of the anion in catalytic Diels-Alder reaction. In short: Fe catalysts are faster but Ru analogues are more stable and can be recovered quantitatively. Rational ligand design is shown to result in a large increase in chiral induction.
Keywords Asymmetric catalysisCycloadditionsIronLewis acidsRuthenium
Identifiers
Full text
Article - document accessible for UNIGE members only Limited access to UNIGE
Structures
Citation
(ISO format)
KUNDIG, Ernst Peter, SAUDAN, C.M., VITON, Florian. Chiral Cyclopentadienyl-Iron and -Ruthenium Lewis Acids Containing the Electron-Poor BIPHOP-F Ligand: a Comparison as Catalysts in an Asymmetric Diels-Alder Reaction. In: Advanced Synthesis and Catalysis, 2001, vol. 343, n° 1, p. 51-56. https://archive-ouverte.unige.ch/unige:7886

135 hits

2 downloads

Update

Deposited on : 2010-06-21

Export document
Format :
Citation style :