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Chiral Cyclopentadienyl-Iron and -Ruthenium Lewis Acids Containing the Electron-Poor BIPHOP-F Ligand: a Comparison as Catalysts in an Asymmetric Diels-Alder Reaction

Published inAdvanced synthesis & catalysis, vol. 343, no. 1, p. 51-56
Publication date2001
Abstract

Chiral iron and ruthenium Lewis acids: analogies and differences between the catalysts and the role of the anion in catalytic Diels-Alder reaction. In short: Fe catalysts are faster but Ru analogues are more stable and can be recovered quantitatively. Rational ligand design is shown to result in a large increase in chiral induction.

Keywords
  • Asymmetric catalysis
  • Cycloadditions
  • Iron
  • Lewis acids
  • Ruthenium
Citation (ISO format)
KUNDIG, Ernst Peter, SAUDAN, C.M., VITON, Florian. Chiral Cyclopentadienyl-Iron and -Ruthenium Lewis Acids Containing the Electron-Poor BIPHOP-F Ligand: a Comparison as Catalysts in an Asymmetric Diels-Alder Reaction. In: Advanced synthesis & catalysis, 2001, vol. 343, n° 1, p. 51–56. doi: 10.1002/1615-4169(20010129)343:1%3C51::AID-ADSC51%3E3.0.CO;2-N
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ISSN of the journal1615-4150
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