Matrix Infrared and Raman Spectroscopic Evidence for Pd(N&gt;2&gt;)&gt;3&gt; in Solid Nitrogen

Ozin, G.A.; Kündig, P.; Huber, Hans Joséf; Moskovits, M.

doi:10.1139/v72-382

Scientific article

English

Matrix Infrared and Raman Spectroscopic Evidence for Pd(N>2>)>3> in Solid Nitrogen

Contributors

Ozin, G.A.; Kündig, P.; Huber, Hans Joséf; Moskovits, M.

Published in

Canadian journal of chemistry, vol. 50, no. 14, p. 2385-2387

Publication date

1972

Abstract

Cocondensation of palladium atoms with 14N2 at 4.2–10 °K leads to the formation of a binary dinitrogen complex. The complex is detected by matrix isolation infrared and Raman spectroscopy. Isotope studies using equimolar 14N2/15N2 mixtures, together with isotope frequency and integrated absorption intensity calculations, suggest that the species is tris-dinitrogen palladium(0), Pd(N2)3.

UNIGE affiliation entities

Not a UNIGE publication

Citation (ISO format)

OZIN, G.A. et al. Matrix Infrared and Raman Spectroscopic Evidence for Pd(N>2>)>3> in Solid Nitrogen. In: Canadian journal of chemistry, 1972, vol. 50, n° 14, p. 2385–2387. doi: 10.1139/v72-382

Article

Identifiers

PID : unige:7879
DOI : 10.1139/v72-382

Journal ISSN

0008-4042

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21/06/2010 10:28:20

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21/06/2010 10:28:20

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14/03/2023 15:47:06

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