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Title

AFM Snapshots of Synthetic Multifunctional Pores with Polyacetylene Blockers: Pseudorotaxanes and Template Effects

Authors
Kumaki, Jiro
Yashima, Eiji
Published in Angewandte Chemie: International Edition. 2005, vol. 44, no. 38, p. 6154-6157
Abstract Caught in a barrel: AFM studies indicate that the host-guest complexes formed between ß-barrel pores and polymer blockers are pseudorotaxanes. The nonstatistical location of the contracted supramolecular barrels on the polymers indicates that the sticky polymer templates insert quickly into the ß barrels (see schematic representation) and then undergo slow motion through the barrels.
Keywords Bioorganic chemistryIon channelsMolecular recognitionScanning probe microscopySupramolecular chemistry
Identifiers
PMID: 16124021
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KUMAKI, Jiro et al. AFM Snapshots of Synthetic Multifunctional Pores with Polyacetylene Blockers: Pseudorotaxanes and Template Effects. In: Angewandte Chemie: International Edition, 2005, vol. 44, n° 38, p. 6154-6157. https://archive-ouverte.unige.ch/unige:7821

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Deposited on : 2010-06-21

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