Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II)

Lacour, Jérôme; Jodry, Jonathan; Ginglinger, Catherine; Torche-Haldimann, Sonya

doi:10.1002/(SICI)1521-3773(19980918)37:17<2379::AID-ANIE2379>3.0.CO;2-C

Scientific article

English

Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II)

ContributorsLacour, Jérôme

; Jodry, Jonathan; Ginglinger, Catherine; Torche-Haldimann, Sonya

Published inAngewandte Chemie, vol. 37, no. 17, p. 2379-2380

Publication date1998

Abstract

Two configurationally stable, chiral anions (TRISPHAT, 1) behave as efficient hosts that control the configuration of a configurationally labile iron(II) complex as the guest with high diastereoselectivity (>96 % de) upon ion pairing. The diastereoselectivity increases with decreasing solvent polarity.

Keywords

Asymmetric amplification
Ion pairs
Iron
Phosphorus
Supramolecular chemistry

NoteParu également dans Angewandte Chemie sous le titre: "Diastereoselektive Ionenpaarbildung des TRISPHAT-Anions mit Tris(4,4'-dimethyl-2,2'-bipyridin)eisen(II)" en 1998, 110(17), 2522-2524

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

LACOUR, Jérôme et al. Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4′-dimethyl-2,2′-bipyridine)iron(II). In: Angewandte Chemie, 1998, vol. 37, n° 17, p. 2379–2380. doi: 10.1002/(SICI)1521-3773(19980918)37:17<2379::AID-ANIE2379>3.0.CO;2-C

Article

Identifiers

PID : unige:7808
DOI : 10.1002/(SICI)1521-3773(19980918)37:17<2379::AID-ANIE2379>3.0.CO;2-C

Journal ISSN1433-7851

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Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II)

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