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Titles listDiastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II)
Titles listDiastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II)
Scientific Article
unige:7808 
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Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II) |
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| Authors | ||
| Published in | Angewandte Chemie: International Edition. 1998, vol. 37, no. 17, p. 2379-2380 | |
| Abstract | Two configurationally stable, chiral anions (TRISPHAT, 1) behave as efficient hosts that control the configuration of a configurationally labile iron(II) complex as the guest with high diastereoselectivity (>96 % de) upon ion pairing. The diastereoselectivity increases with decreasing solvent polarity. | |
| Abstract | Zwei konfigurativ stabile, chirale Anionen (TRISPHAT 1) beeinflussen bei der Ionenpaarbildung mit einem konfigurativ labilen Eisen(II)-Komplex dessen Konfiguration mit hoher Diastereoselektivität (>96 % de). Dabei steigt der Diastereomerenüberschuß mit abnehmender Lösungsmittelpolarität. | |
| Keywords | Asymmetric amplification — Ion pairs — Iron — Phosphorus — Supramolecular chemistry | |
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| Note | Paru également dans Angewandte Chemie sous le titre: "Diastereoselektive Ionenpaarbildung des TRISPHAT-Anions mit Tris(4,4'-dimethyl-2,2'-bipyridin)eisen(II)" en 1998, 110(17), 2522-2524 | |
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| Citation (ISO format) | LACOUR, Jérôme et al. Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II). In: Angewandte Chemie: International Edition, 1998, vol. 37, n° 17, p. 2379-2380. doi: 10.1002/(SICI)1521-3773(19980918)37:17<2379::AID-ANIE2379>3.0.CO;2-C https://archive-ouverte.unige.ch/unige:7808 |
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