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Scientific article
English

Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II)

Published inAngewandte Chemie, vol. 37, no. 17, p. 2379-2380
Publication date1998
Abstract

Two configurationally stable, chiral anions (TRISPHAT, 1) behave as efficient hosts that control the configuration of a configurationally labile iron(II) complex as the guest with high diastereoselectivity (>96 % de) upon ion pairing. The diastereoselectivity increases with decreasing solvent polarity.

Keywords
  • Asymmetric amplification
  • Ion pairs
  • Iron
  • Phosphorus
  • Supramolecular chemistry
NoteParu également dans Angewandte Chemie sous le titre: "Diastereoselektive Ionenpaarbildung des TRISPHAT-Anions mit Tris(4,4'-dimethyl-2,2'-bipyridin)eisen(II)" en 1998, 110(17), 2522-2524
Citation (ISO format)
LACOUR, Jérôme et al. Diastereoselective Ion Pairing of TRISPHAT Anions and Tris(4,4′-dimethyl-2,2′-bipyridine)iron(II). In: Angewandte Chemie, 1998, vol. 37, n° 17, p. 2379–2380. doi: 10.1002/(SICI)1521-3773(19980918)37:17<2379::AID-ANIE2379>3.0.CO;2-C
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