Stopping a Chromium Carousel: X-Ray Crystallographic and Variable-Temperature 13C-NMR Studies on Dicarbonyl(hexaethylbenzene)thiocarbonylchromium(0) and Related Complexes

McGlinchey, Michael J.; Fletcher, John L.; Sayer, Brian G.; Bougeard, Peter; Faggiani, Romolo; Lock, Colin J.L.; Bain, Alex D.; Rodger, Charles; Kundig, Ernst Peter; Astruc, Didier; Hamon, Jean-René; Le Maux, Paul; Top, Siden; Jaouen, Gérard

doi:10.1039/C39830000634

Scientific article

English

Stopping a Chromium Carousel: X-Ray Crystallographic and Variable-Temperature 13C-NMR Studies on Dicarbonyl(hexaethylbenzene)thiocarbonylchromium(0) and Related Complexes

ContributorsMcGlinchey, Michael J.; Fletcher, John L.; Sayer, Brian G.; Bougeard, Peter; Faggiani, Romolo; Lock, Colin J.L.; Bain, Alex D.; Rodger, Charles; Kundig, Ernst Peter; Astruc, Didier; Hamon, Jean-René; Le Maux, Paul; Top, Siden; Jaouen, Gérard

Published inJournal of the Chemical Society. Chemical communications, no. 11, p. 634-636

Publication date1983

Abstract

The low temperature 13C n.m.r. spectrum of (C6Et6)Cr(CO)2CS shows the molecule to have Cs symmetry as it does in the solid state; this result provides the first clear evidence of cessation of tripodal rotation in a neutral half-sandwich compound of Cr.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MCGLINCHEY, Michael J. et al. Stopping a Chromium Carousel: X-Ray Crystallographic and Variable-Temperature 13C-NMR Studies on Dicarbonyl(hexaethylbenzene)thiocarbonylchromium(0) and Related Complexes. In: Journal of the Chemical Society. Chemical communications, 1983, n° 11, p. 634–636. doi: 10.1039/C39830000634

Article

Identifiers

PID : unige:7797
DOI : 10.1039/C39830000634

Journal ISSN0022-4936

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Stopping a Chromium Carousel: X-Ray Crystallographic and Variable-Temperature 13C-NMR Studies on Dicarbonyl(hexaethylbenzene)thiocarbonylchromium(0) and Related Complexes

The low temperature 13C n.m.r. spectrum of (C6Et6)Cr(CO)2CS shows the molecule to have Cs symmetry as it does in the solid state; this result provides the first clear evidence of cessation of tripodal rotation in a neutral half-sandwich compound of Cr.

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