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Stopping a Chromium Carousel: X-Ray Crystallographic and Variable-Temperature 13C-NMR Studies on Dicarbonyl(hexaethylbenzene)thiocarbonylchromium(0) and Related Complexes

Authors
McGlinchey, Michael J.
Fletcher, John L.
Sayer, Brian G.
Bougeard, Peter
Faggiani, Romolo
Lock, Colin J.L.
Bain, Alex D.
Rodger, Charles
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Published in Journal of the Chemical Society. Chemical Communications. 1983, no. 11, p. 634-636
Abstract The low temperature 13C n.m.r. spectrum of (C6Et6)Cr(CO)2CS shows the molecule to have Cs symmetry as it does in the solid state; this result provides the first clear evidence of cessation of tripodal rotation in a neutral half-sandwich compound of Cr.
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MCGLINCHEY, Michael J. et al. Stopping a Chromium Carousel: X-Ray Crystallographic and Variable-Temperature 13C-NMR Studies on Dicarbonyl(hexaethylbenzene)thiocarbonylchromium(0) and Related Complexes. In: Journal of the Chemical Society. Chemical Communications, 1983, n° 11, p. 634-636. https://archive-ouverte.unige.ch/unige:7797

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Deposited on : 2010-06-21

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