The Transformation of Arenes into Acetyl Dienes via Nucleophilic Addition to Arene-Cr(CO)&gt;3&gt; Complexes and Trapping with Mel

Kundig, Ernst Peter; Simmons, Dana P.

doi:10.1039/C39830001320

Scientific article

English

The Transformation of Arenes into Acetyl Dienes via Nucleophilic Addition to Arene-Cr(CO)>3> Complexes and Trapping with Mel

ContributorsKundig, Ernst Peter; Simmons, Dana P.

Published inJournal of the Chemical Society. Chemical communications, no. 22, p. 1320-1322

Publication date1983

Abstract

Anionic cyclohexadienyl–Cr(CO)3 complexes, formed by addition of reactive carbanions to benzene–Cr(CO)3 and naphthalene–Cr(CO)3 complexes, react with Mel by addition and carbonylation to yield disubstituted cyclohexadienes and dihydronaphthalenes, respectively.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

KUNDIG, Ernst Peter, SIMMONS, Dana P. The Transformation of Arenes into Acetyl Dienes via Nucleophilic Addition to Arene-Cr(CO)>3> Complexes and Trapping with Mel. In: Journal of the Chemical Society. Chemical communications, 1983, n° 22, p. 1320–1322. doi: 10.1039/C39830001320

Article

Identifiers

PID : unige:7796
DOI : 10.1039/C39830001320

Journal ISSN0022-4936

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The Transformation of Arenes into Acetyl Dienes via Nucleophilic Addition to Arene-Cr(CO)>3> Complexes and Trapping with Mel

Anionic cyclohexadienyl–Cr(CO)3 complexes, formed by addition of reactive carbanions to benzene–Cr(CO)3 and naphthalene–Cr(CO)3 complexes, react with Mel by addition and carbonylation to yield disubstituted cyclohexadienes and dihydronaphthalenes, respectively.

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