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unige:7788 
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Chiral Anion Mediated Asymmetric Chemistry |
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| Published in | Chimia. 2002, vol. 56, no. 12, p. 672-675 | |
| Abstract | The octahedral geometry of pentavalent hexacoordinated phosphorus allows the formation of chiral anions by complexation of the central phosphorus atom with three bidentate ligands. These simple-to-make derivatives can be combined with chiral cations and often display efficient NMR chiral shift, resolving and asymmetry-inducing properties. This paper is a short review of our research efforts directed towards the development of chiral anion mediated asymmetric chemistry. | |
| Keywords | Chiral recognition — Hexacoordinated phosphorus — Ion pairing — Nmr — Supramolecular chemistry | |
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| Citation (ISO format) | LACOUR, Jérôme. Chiral Anion Mediated Asymmetric Chemistry. In: Chimia, 2002, vol. 56, n° 12, p. 672-675. doi: 10.2533/000942902777679902 https://archive-ouverte.unige.ch/unige:7788 |
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