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Chiral Anion Mediated Asymmetric Chemistry

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Published in Chimia. 2002, vol. 56, no. 12, p. 672-675
Abstract The octahedral geometry of pentavalent hexacoordinated phosphorus allows the formation of chiral anions by complexation of the central phosphorus atom with three bidentate ligands. These simple-to-make derivatives can be combined with chiral cations and often display efficient NMR chiral shift, resolving and asymmetry-inducing properties. This paper is a short review of our research efforts directed towards the development of chiral anion mediated asymmetric chemistry.
Keywords Chiral recognitionHexacoordinated phosphorusIon pairingNmrSupramolecular chemistry
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LACOUR, Jérôme. Chiral Anion Mediated Asymmetric Chemistry. In: Chimia, 2002, vol. 56, n° 12, p. 672-675. https://archive-ouverte.unige.ch/unige:7788

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Deposited on : 2010-06-21

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