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Scientific article
English

Chiral Anion Mediated Asymmetric Chemistry

ContributorsLacour, Jérôme
Published inChimia, vol. 56, no. 12, p. 672-675
Publication date2002
Abstract

The octahedral geometry of pentavalent hexacoordinated phosphorus allows the formation of chiral anions by complexation of the central phosphorus atom with three bidentate ligands. These simple-to-make derivatives can be combined with chiral cations and often display efficient NMR chiral shift, resolving and asymmetry-inducing properties. This paper is a short review of our research efforts directed towards the development of chiral anion mediated asymmetric chemistry.

Keywords
  • Chiral recognition
  • Hexacoordinated phosphorus
  • Ion pairing
  • Nmr
  • Supramolecular chemistry
Citation (ISO format)
LACOUR, Jérôme. Chiral Anion Mediated Asymmetric Chemistry. In: Chimia, 2002, vol. 56, n° 12, p. 672–675. doi: 10.2533/000942902777679902
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ISSN of the journal0009-4293
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