Scientific article

Diversity Oriented Synthesis of Chiral Hexacoordinated Phosphate Anions

Published inEuropean journal of organic chemistry, vol. 2002, no. 21, p. 3580-3588
Publication date2002

Novel hexacoordinated phosphate anions consisting of a central phosphorus(v) atom and at least one tetrachloropyrocatechol ligand can be simply prepared in modest to decent yields (37-71%) as their dimethylammonium salts following a one-pot process and with simple, usually commercially available, starting materials. A variety of symmetrical diones (α-diketones or ortho-quinones) can be used in this protocol and the structurally-diverse products are chemically stable when two tetrachloropyrocatechol ligands surround the P atom.

  • Oxo ligands
  • Phosphorus
  • Anions
  • Synthesis design
  • Octahedral geometry
Citation (ISO format)
LACOUR, Jérôme, CONSTANT, Samuel Claude, HEBBE, Virginie. Diversity Oriented Synthesis of Chiral Hexacoordinated Phosphate Anions. In: European journal of organic chemistry, 2002, vol. 2002, n° 21, p. 3580–3588. doi: 10.1002/1099-0690(200211)2002:21%3C3580::AID-EJOC3580%3E3.0.CO;2-A
Main files (1)
ISSN of the journal1099-0690

Technical informations

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