en
Scientific article
English

Diversity Oriented Synthesis of Chiral Hexacoordinated Phosphate Anions

Published inEuropean journal of organic chemistry, vol. 2002, no. 21, p. 3580-3588
Publication date2002
Abstract

Novel hexacoordinated phosphate anions consisting of a central phosphorus(v) atom and at least one tetrachloropyrocatechol ligand can be simply prepared in modest to decent yields (37-71%) as their dimethylammonium salts following a one-pot process and with simple, usually commercially available, starting materials. A variety of symmetrical diones (α-diketones or ortho-quinones) can be used in this protocol and the structurally-diverse products are chemically stable when two tetrachloropyrocatechol ligands surround the P atom.

Keywords
  • Oxo ligands
  • Phosphorus
  • Anions
  • Synthesis design
  • Octahedral geometry
Citation (ISO format)
LACOUR, Jérôme, CONSTANT, Samuel Claude, HEBBE, Virginie. Diversity Oriented Synthesis of Chiral Hexacoordinated Phosphate Anions. In: European journal of organic chemistry, 2002, vol. 2002, n° 21, p. 3580–3588. doi: 10.1002/1099-0690(200211)2002:21%3C3580::AID-EJOC3580%3E3.0.CO;2-A
Main files (1)
Article
accessLevelRestricted
ISSN of the journal1099-0690
518views
0downloads

Technical informations

Creation06/21/2010 10:27:43 AM
First validation06/21/2010 10:27:43 AM
Update time03/14/2023 3:46:39 PM
Status update03/14/2023 3:46:39 PM
Last indexation02/12/2024 6:41:54 PM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack