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unige:7783 
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Diversity Oriented Synthesis of Chiral Hexacoordinated Phosphate Anions |
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| Published in | European Journal of Organic Chemistry. 2002, vol. 2002, no. 21, p. 3580-3588 | |
| Abstract | Novel hexacoordinated phosphate anions consisting of a central phosphorus(v) atom and at least one tetrachloropyrocatechol ligand can be simply prepared in modest to decent yields (37-71%) as their dimethylammonium salts following a one-pot process and with simple, usually commercially available, starting materials. A variety of symmetrical diones (α-diketones or ortho-quinones) can be used in this protocol and the structurally-diverse products are chemically stable when two tetrachloropyrocatechol ligands surround the P atom. | |
| Keywords | Oxo ligands — Phosphorus — Anions — Synthesis design — Octahedral geometry | |
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| Citation (ISO format) | LACOUR, Jérôme, CONSTANT, Samuel Claude, HEBBE, Virginie. Diversity Oriented Synthesis of Chiral Hexacoordinated Phosphate Anions. In: European Journal of Organic Chemistry, 2002, vol. 2002, n° 21, p. 3580-3588. doi: 10.1002/1099-0690(200211)2002:21%3C3580::AID-EJOC3580%3E3.0.CO;2-A https://archive-ouverte.unige.ch/unige:7783 |
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