UNIGE document Scientific Article
previous document  unige:7783  next document
add to browser collection

Diversity Oriented Synthesis of Chiral Hexacoordinated Phosphate Anions

Published in European Journal of Organic Chemistry. 2002, vol. 2002, no. 21, p. 3580-3588
Abstract Novel hexacoordinated phosphate anions consisting of a central phosphorus(v) atom and at least one tetrachloropyrocatechol ligand can be simply prepared in modest to decent yields (37-71%) as their dimethylammonium salts following a one-pot process and with simple, usually commercially available, starting materials. A variety of symmetrical diones (α-diketones or ortho-quinones) can be used in this protocol and the structurally-diverse products are chemically stable when two tetrachloropyrocatechol ligands surround the P atom.
Keywords Oxo ligandsPhosphorusAnionsSynthesis designOctahedral geometry
Full text
Article - document accessible for UNIGE members only Limited access to UNIGE
(ISO format)
LACOUR, Jérôme, CONSTANT, Samuel Claude, HEBBE, Virginie. Diversity Oriented Synthesis of Chiral Hexacoordinated Phosphate Anions. In: European Journal of Organic Chemistry, 2002, vol. 2002, n° 21, p. 3580-3588. doi: 10.1002/1099-0690(200211)2002:21%3C3580::AID-EJOC3580%3E3.0.CO;2-A https://archive-ouverte.unige.ch/unige:7783

440 hits



Deposited on : 2010-06-21

Export document
Format :
Citation style :