TRISPHAT Salts. Efficient NMR Chiral Shift and Resolving Agents for Substituted Cyclometallated Ruthenium Bis(diimine) Complexes

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Title		TRISPHAT Salts. Efficient NMR Chiral Shift and Resolving Agents for Substituted Cyclometallated Ruthenium Bis(diimine) Complexes
Authors		Monchaud, David Lacour, Jérôme Coudret, Christophe Fraysse, Sandrine
Published in		Journal of organometallic chemistry. 2001, vol. 624, no. 1-2, p. 388-391
Abstract		The determination of the enantiomeric purity of monocationic ruthenium(II) cyclometallated complexes is easily carried out by 1H-NMR analysis using a TRISPHAT salt as a diamagnetic chiral shift reagent. Resolution of the organometallic complexes can be conveniently carried by preparative thin layer chromatography using TRISPHAT as a chiral counter-ion.
Keywords		Resolution — NMR enantiomeric purity determination — Ion pairing
Identifiers		DOI: 10.1016/S0022-328X(01)00685-4
Note		special issue for J.-F. Normant
Full text		Article - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		MONCHAUD, David et al. TRISPHAT Salts. Efficient NMR Chiral Shift and Resolving Agents for Substituted Cyclometallated Ruthenium Bis(diimine) Complexes. In: Journal of organometallic chemistry, 2001, vol. 624, n° 1-2, p. 388-391. doi: 10.1016/S0022-328X(01)00685-4 https://archive-ouverte.unige.ch/unige:7758

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Deposited on : 2010-06-21

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