UNIGE document Scientific Article
previous document  unige:7723  next document
add to browser collection
Title

Construction, substitution, and sorting of metallo-organic structures via subcomponent self-assembly

Author
Published in Accounts of Chemical Research. 2007, vol. 40, no. 2, p. 103-112
Abstract Subcomponent self-assembly allows the construction of complex architectures from simple building blocks via formation of covalent bonds around metal templates. Since both covalent and coordinative bonds are formed reversibly, a wealth of rearrangement reactions is possible involving substitution at both intraligand (often C==N) and metal-ligand (N -> metal) bonds. If the possibilities latent within a set of subcomponents and metal ions are understood, one may also select specific structures from among dynamic libraries of products. The parallel preparation of structures from “nonorthogonal” mixtures of subcomponents is also possible, as is the direction of subcomponents to specific sites within product structures.
Identifiers
PMID: 17309191
Full text
Article - document accessible for UNIGE members only Limited access to UNIGE
Structures
Citation
(ISO format)
NITSCHKE, Jonathan. Construction, substitution, and sorting of metallo-organic structures via subcomponent self-assembly. In: Accounts of Chemical Research, 2007, vol. 40, n° 2, p. 103-112. https://archive-ouverte.unige.ch/unige:7723

206 hits

0 download

Update

Deposited on : 2010-06-21

Export document
Format :
Citation style :