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ChemInform Abstract: A Mild and Efficient CH2-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Troeger Bases

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Published in Chem Inform. 2015, vol. 46, no. 43
Abstract Oxidation of ethano-Troeger bases (I) and (III) with DDQ in wet nitromethane results in a highly enantiospecific methylene extrusion to afford ring contracted products (II) and (IV) which are significantly more configurationally stable than regular Troeger bases.
Keywords Bridged compounds (heterocyclic compounds)Ring contraction
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Research groups Groupe Bürgi
Groupe Lacour
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PUJARI, Sandip et al. ChemInform Abstract: A Mild and Efficient CH2-Extrusion Reaction for the Enantiospecific Synthesis of Highly Configurationally Stable Troeger Bases. In: Chem Inform, 2015, vol. 46, n° 43. doi: 10.1002/chin.201543111 https://archive-ouverte.unige.ch/unige:76521

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Deposited on : 2015-10-26

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