Scientific article

English

Pd₂Au₃₆(SR)₂₄ cluster: structure studies

ContributorsZhang, Bei; Kaziz, Sameh; Li, Houhua; Wodka, Dawid; Malola, Sami; Safonova, Olga; Nachtegaal, Maarten; Mazet, Clement; Dolamic, Igor; Llorca, Jordi; Kalenius, Elina; Lawson Daku, Latevi Max; Hakkinen, Hannu; Buergi, Thomas; Barrabes Rabanal, Noëlia

Published inNanoscale, vol. 7, no. 40, p. 17012-17019

Publication date2015

Abstract

The location of the Pd atoms in Pd2Au36(SC2H4Ph)24, is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd–S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.

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Citation (ISO format)

ZHANG, Bei et al. Pd<sub>2</sub>Au<sub>36</sub>(SR)<sub>24</sub> cluster: structure studies. In: Nanoscale, 2015, vol. 7, n° 40, p. 17012–17019. doi: 10.1039/C5NR04324G

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PID : unige:75923
DOI : 10.1039/C5NR04324G

Commercial URLhttp://xlink.rsc.org/?DOI=C5NR04324G

ISSN of the journal2040-3372

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Creation10/09/2015 10:50:00 AM

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