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Pd2Au36(SR)24 cluster: structure studies

Kaziz, Sameh
Malola, Sami
Safonova, Olga
Nachtegaal, Maarten
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Published in Nanoscale. 2015, vol. 7, no. 40, p. 17012-17019
Abstract The location of the Pd atoms in Pd2Au36(SC2H4Ph)24, is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd–S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.
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Other version: http://xlink.rsc.org/?DOI=C5NR04324G
Research groups Groupe Bürgi
Groupe Mazet
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ZHANG, Bei et al. Pd2Au36(SR)24 cluster: structure studies. In: Nanoscale, 2015, vol. 7, n° 40, p. 17012-17019. doi: 10.1039/C5NR04324G https://archive-ouverte.unige.ch/unige:75923

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Deposited on : 2015-10-12

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