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Access to enantioenriched 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter by Pd-catalyzed asymmetric intermolecular Heck reaction

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Published in Chemical Science. 2015, vol. 6, no. 8, p. 4807-4811
Abstract A palladium-catalyzed intermolecular asymmetric Heck reaction with dihydrofurans with a trisubstituted double bond is reported. The use of two different chiral ligands provides access to valuable 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter with high levels of regio- and enantiocontrol.
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Research group Groupe Mazet
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BORRAJO CALLEJA, Gustavo et al. Access to enantioenriched 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter by Pd-catalyzed asymmetric intermolecular Heck reaction. In: Chemical Science, 2015, vol. 6, n° 8, p. 4807-4811. https://archive-ouverte.unige.ch/unige:74172

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Deposited on : 2015-07-16

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