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Enantioselective olefin epoxidation using novel biphenyl and binaphthyl azepines and azepinium salts

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Lauper, Cédric
Ditrich, Klaus
Published in Tetrahedron: Asymmetry. 2006, vol. 17, no. 16, p. 2334-2338
Abstract Homologous biphenyl and (diastereomeric) binaphthyl tertiary azepines and quaternary iminium salts were prepared from (S)- and (R)-3,3-dimethylbutan-2-amine. Both the amines and iminium ions behave as effective catalysts for the enantioselective epoxidation of unfunctionalized olefins (ee up to 87%).
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VACHON, Jérôme et al. Enantioselective olefin epoxidation using novel biphenyl and binaphthyl azepines and azepinium salts. In: Tetrahedron: Asymmetry, 2006, vol. 17, n° 16, p. 2334-2338. https://archive-ouverte.unige.ch/unige:7058

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Deposited on : 2010-06-18

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