Enantioselective olefin epoxidation using novel biphenyl and binaphthyl azepines and azepinium salts

Vachon, Jérôme; Lauper, Cédric; Ditrich, Klaus; Lacour, Jérôme

doi:10.1016/j.tetasy.2006.08.018

Article scientifique

Anglais

Enantioselective olefin epoxidation using novel biphenyl and binaphthyl azepines and azepinium salts

Contributeurs/tricesVachon, Jérôme; Lauper, Cédric; Ditrich, Klaus; Lacour, Jérôme

Publié dansTetrahedron: asymmetry, vol. 17, no. 16, p. 2334-2338

Date de publication2006

Résumé

Homologous biphenyl and (diastereomeric) binaphthyl tertiary azepines and quaternary iminium salts were prepared from (S)- and (R)-3,3-dimethylbutan-2-amine. Both the amines and iminium ions behave as effective catalysts for the enantioselective epoxidation of unfunctionalized olefins (ee up to 87%).

Structure d'affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (format ISO)

VACHON, Jérôme et al. Enantioselective olefin epoxidation using novel biphenyl and binaphthyl azepines and azepinium salts. In: Tetrahedron: asymmetry, 2006, vol. 17, n° 16, p. 2334–2338. doi: 10.1016/j.tetasy.2006.08.018

Article

Identifiants

PID : unige:7058
DOI : 10.1016/j.tetasy.2006.08.018

ISSN du journal0957-4166

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Enantioselective olefin epoxidation using novel biphenyl and binaphthyl azepines and azepinium salts

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