Scientific article
English

Dinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of α,β-unsaturated Imides

Published inAngewandte Chemie, vol. 47, no. 9, p. 1762-1765
Publication date2008
Abstract

Covalently linked dinuclear {(salen)Al} complexes catalyze the conjugate cyanation of,-unsaturated imides with several orders of magnitude greater reactivity over the mononuclear analogue, and with comparable enantioselectivity. Imides that were completely unreactive with homo- and heterobimetallic combinations of mononuclear catalysts can now be converted into the corresponding cyanation products with high enantiomeric excess.

Citation (ISO format)
MAZET, Clement, JACOBSEN, Eric N. Dinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of α,β-unsaturated Imides. In: Angewandte Chemie, 2008, vol. 47, n° 9, p. 1762–1765. doi: 10.1002/anie.200704461
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