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Titles listDinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of α,β-unsaturated Imides
Titles listDinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of α,β-unsaturated Imides
Scientific Article
unige:7053 
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Dinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of α,β-unsaturated Imides |
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| Authors | ||
| Published in | Angewandte Chemie: International Edition. 2008, vol. 47, no. 9, p. 1762-1765 | |
| Abstract | Covalently linked dinuclear {(salen)Al} complexes catalyze the conjugate cyanation of,-unsaturated imides with several orders of magnitude greater reactivity over the mononuclear analogue, and with comparable enantioselectivity. Imides that were completely unreactive with homo- and heterobimetallic combinations of mononuclear catalysts can now be converted into the corresponding cyanation products with high enantiomeric excess. | |
| Identifiers | PMID: 18219639 | |
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| Citation (ISO format) | MAZET, Clement, JACOBSEN, Eric N. Dinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of α,β-unsaturated Imides. In: Angewandte Chemie: International Edition, 2008, vol. 47, n° 9, p. 1762-1765. https://archive-ouverte.unige.ch/unige:7053 |
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