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Title

Dinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of α,β-unsaturated Imides

Authors
Jacobsen, Eric N.
Published in Angewandte Chemie: International Edition. 2008, vol. 47, no. 9, p. 1762-1765
Abstract Covalently linked dinuclear {(salen)Al} complexes catalyze the conjugate cyanation of,-unsaturated imides with several orders of magnitude greater reactivity over the mononuclear analogue, and with comparable enantioselectivity. Imides that were completely unreactive with homo- and heterobimetallic combinations of mononuclear catalysts can now be converted into the corresponding cyanation products with high enantiomeric excess.
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PMID: 18219639
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MAZET, Clement, JACOBSEN, Eric N. Dinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of α,β-unsaturated Imides. In: Angewandte Chemie: International Edition, 2008, vol. 47, n° 9, p. 1762-1765. https://archive-ouverte.unige.ch/unige:7053

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Deposited on : 2010-06-18

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