Comparison of the NMR Enantiodifferentiation of a Chiral Ruthenium(II) Complex of C2 Symmetry Using the TRISPHAT Anion and a Lanthanide Shift Reagent

Browse by...

Deposit

Highlights

More informations

Title		Comparison of the NMR Enantiodifferentiation of a Chiral Ruthenium(II) Complex of C2 Symmetry Using the TRISPHAT Anion and a Lanthanide Shift Reagent
Authors		Bruylants, Gilles Bresson, Carole Boisdenghien, Arnaud Pierard, Frédéric Kirsch-De Mesmaeker, André Lacour, Jérôme Bartik, Kristin
Published in		New Journal of Chemistry. 2003, vol. 27, no. 4, p. 748-751
Abstract		The tris[tetrachlorobenzenediolato]phosphate(V) anion (TRISPHAT) is known to be an efficient NMR chiral shift agent for various chiral cationic species. Here we compare the efficiency of TRISPHAT and of a chiral lanthanide shift reagent for the determination of the enantiomeric purity of the chiral building block [Ru(phen)2py2]2+ which possesses C2 symmetry. We also discuss our results in terms of the geometry of interaction between the Ru(II) complex and the TRISPHAT anion.
Identifiers		DOI: 10.1039/b211419d
Full text		Article - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		BRUYLANTS, Gilles et al. Comparison of the NMR Enantiodifferentiation of a Chiral Ruthenium(II) Complex of C2 Symmetry Using the TRISPHAT Anion and a Lanthanide Shift Reagent. In: New Journal of Chemistry, 2003, vol. 27, n° 4, p. 748-751. https://archive-ouverte.unige.ch/unige:7022