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Title

Chiral Induction in a Ribose-Decorated Metallostar through Intrinsic and Interionic Diastereomeric Interactions

Authors
Constable, Edwin C.
Housecroft, Catherine E.
Mahmood, Azad
Published in Inorganic Chemistry. 2004, vol. 43, p. 4817-4819
Abstract A ribose-functionalized bpy ligand has been prepared and shown to give modest diastereomeric excesses of ?-[FeL3]2+ complexes; interconversion of ? and ? cations is relatively fast, and in CHCl3, the favored complexes with ?- or ?-TRISPHAT counterions are homochiral, (?+?-) or (?+?-). In the case of the ?-TRISPHAT salt, a single diastereomer is observed (de = 96%).
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PMID: 15285654
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CONSTABLE, Edwin C. et al. Chiral Induction in a Ribose-Decorated Metallostar through Intrinsic and Interionic Diastereomeric Interactions. In: Inorganic Chemistry, 2004, vol. 43, p. 4817-4819. https://archive-ouverte.unige.ch/unige:7019

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Deposited on : 2010-06-18

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