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Scientific article
English

Chiral Induction in a Ribose-Decorated Metallostar through Intrinsic and Interionic Diastereomeric Interactions

Published inInorganic chemistry, vol. 43, p. 4817-4819
Publication date2004
Abstract

A ribose-functionalized bpy ligand has been prepared and shown to give modest diastereomeric excesses of ?-[FeL3]2+ complexes; interconversion of ? and ? cations is relatively fast, and in CHCl3, the favored complexes with ?- or ?-TRISPHAT counterions are homochiral, (?+?-) or (?+?-). In the case of the ?-TRISPHAT salt, a single diastereomer is observed (de = 96%).

Citation (ISO format)
CONSTABLE, Edwin C. et al. Chiral Induction in a Ribose-Decorated Metallostar through Intrinsic and Interionic Diastereomeric Interactions. In: Inorganic chemistry, 2004, vol. 43, p. 4817–4819. doi: 10.1021/ic049392r
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ISSN of the journal0020-1669
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