Chiral Induction in a Ribose-Decorated Metallostar through Intrinsic and Interionic Diastereomeric Interactions

Constable, Edwin C.; Frantz, Richard; Housecroft, Catherine E.; Lacour, Jérôme; Mahmood, Azad

doi:10.1021/ic049392r

Scientific article

English

Chiral Induction in a Ribose-Decorated Metallostar through Intrinsic and Interionic Diastereomeric Interactions

ContributorsConstable, Edwin C.; Frantz, Richard; Housecroft, Catherine E.; Lacour, Jérôme

; Mahmood, Azad

Published inInorganic chemistry, vol. 43, p. 4817-4819

Publication date2004

Abstract

A ribose-functionalized bpy ligand has been prepared and shown to give modest diastereomeric excesses of ?-[FeL3]2+ complexes; interconversion of ? and ? cations is relatively fast, and in CHCl3, the favored complexes with ?- or ?-TRISPHAT counterions are homochiral, (?+?-) or (?+?-). In the case of the ?-TRISPHAT salt, a single diastereomer is observed (de = 96%).

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

CONSTABLE, Edwin C. et al. Chiral Induction in a Ribose-Decorated Metallostar through Intrinsic and Interionic Diastereomeric Interactions. In: Inorganic chemistry, 2004, vol. 43, p. 4817–4819. doi: 10.1021/ic049392r

Article

Identifiers

PID : unige:7019
DOI : 10.1021/ic049392r
PMID : 15285654

Journal ISSN0020-1669

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Chiral Induction in a Ribose-Decorated Metallostar through Intrinsic and Interionic Diastereomeric Interactions

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