Enantioselective [1,2]-Stevens rearrangement of quaternary ammonium salts : a mechanistic evaluation

Gonçalves-Farbos, Maria-Héléna; Vial, Laurent; Lacour, Jérôme

doi:10.1039/b716488b

Scientific article

English

Enantioselective [1,2]-Stevens rearrangement of quaternary ammonium salts : a mechanistic evaluation

ContributorsGonçalves-Farbos, Maria-Héléna; Vial, Laurent; Lacour, Jérôme

Published inChemical communications, no. 7, p. 829-831

Publication date2008

Abstract

Using a supramolecular asymmetric ion pairing strategy, an enantioselective [1,2]-Stevens is feasible on substrates devoid of stereogenic quaternary nitrogen atoms.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

GONÇALVES-FARBOS, Maria-Héléna, VIAL, Laurent, LACOUR, Jérôme. Enantioselective [1,2]-Stevens rearrangement of quaternary ammonium salts : a mechanistic evaluation. In: Chemical communications, 2008, n° 7, p. 829–831. doi: 10.1039/b716488b

Article (Published version)

Identifiers

PID : unige:7
DOI : 10.1039/b716488b
PMID : 18253518

Journal ISSN1359-7345

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Creation29/10/2008 11:37:28

First validation29/10/2008 11:37:28

Update time14/03/2023 14:56:23

Status update14/03/2023 14:56:23

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Enantioselective [1,2]-Stevens rearrangement of quaternary ammonium salts : a mechanistic evaluation

Using a supramolecular asymmetric ion pairing strategy, an enantioselective [1,2]-Stevens is feasible on substrates devoid of stereogenic quaternary nitrogen atoms.

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