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1,2-Asymmetric Induction in Radical Reactions of β-Amino Acid Derivatives

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Xu, Long-He
Published in Tetrahedron Letters. 1995, vol. 36, no. 23, p. 4047-4050
Abstract Carbon centered radicals adjacent to a chiral amine and generated by the addition of alkyl radicals to racemic or enantiomerically pure acrylates 1 react with tributyltin hydride in high yields and moderate to good diastereoselectivity. 1,2-Asymmetric induction depends on the nature of the groups at the stereogenic and the prochiral center and is remarkably sensitive to changes in the aryl-o-substituent.
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KUNDIG, Ernst Peter, XU, Long-He, ROMANENS, Patrick. 1,2-Asymmetric Induction in Radical Reactions of β-Amino Acid Derivatives. In: Tetrahedron Letters, 1995, vol. 36, n° 23, p. 4047-4050. https://archive-ouverte.unige.ch/unige:6998

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Deposited on : 2010-06-18

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