UNIGE document Scientific Article
previous document  unige:6993  next document
add to browser collection
Title

Synthetic Ion Channels with Rigid-Rod π-Stack Architecture that Open in Response to Charge-Transfer Complex Formation

Authors
Published in Journal of the American Chemical Society. 2005, vol. 127, no. 18, p. 6528-6529
Abstract We describe the design, synthesis, and evaluation of synthetic ion channels with a new rigid-rod p-stack architecture that open in response to guest binding by aromatic electron donor-acceptor interactions. Highly cooperative and highly selective ligand gating is shown to yield anion selective, small ion channels that have the characteristic plum color of the charge-transfer complexes formed between the dialkoxynaphthalene ligands and the stacked naphthalenediimide acceptors of the channel.
Identifiers
Full text
Article - document accessible for UNIGE members only Limited access to UNIGE
Structures
Citation
(ISO format)
TALUKDAR, Pinaki et al. Synthetic Ion Channels with Rigid-Rod π-Stack Architecture that Open in Response to Charge-Transfer Complex Formation. In: Journal of the American Chemical Society, 2005, vol. 127, n° 18, p. 6528-6529. https://archive-ouverte.unige.ch/unige:6993

218 hits

20 downloads

Update

Deposited on : 2010-06-18

Export document
Format :
Citation style :