Fluorinated TRISPHAT Anions: Spectroscopic Probes for Detailed Asymmetric Ion Pairing Studies

Frantz, Richard; Pinto, André; Constant, Samuel Claude; Bernardinelli, Gérald Hugues; Lacour, Jérôme

doi:10.1002/anie.200500862

Scientific article

English

Fluorinated TRISPHAT Anions: Spectroscopic Probes for Detailed Asymmetric Ion Pairing Studies

Contributors

Frantz, Richard; Pinto, André; Constant, Samuel Claude; Bernardinelli, Gérald Hugues; Lacour, Jérôme

Published in

Angewandte Chemie, vol. 44, no. 32, p. 5060-5064

Publication date

2005

Abstract

Placing fluorine atoms at selected positions allows enantiopure hexacoordinate phosphate anions to behave as effective chiral solvating and resolving agents for RuII complexes (the structure of one of the anions is shown: F: yellow; O: red; Cl: green; P: purple). The structural features of the asymmetric ion pairing can be determined by NMR spectroscopy owing to the presence of the fluorine atoms.

Keywords

Chiral resolution
Ion pairs
NMR spectroscopy
Phosphates
Ruthenium

UNIGE affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

FRANTZ, Richard et al. Fluorinated TRISPHAT Anions: Spectroscopic Probes for Detailed Asymmetric Ion Pairing Studies. In: Angewandte Chemie, 2005, vol. 44, n° 32, p. 5060–5064. doi: 10.1002/anie.200500862

Article

Identifiers

PID : unige:6981
DOI : 10.1002/anie.200500862
PMID : 16010701

Journal ISSN

1433-7851

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18/06/2010 08:54:53

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18/06/2010 08:54:53

Update

14/03/2023 15:30:33

Status update

14/03/2023 15:30:33

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10/06/2025 21:33:56

Fluorinated TRISPHAT Anions: Spectroscopic Probes for Detailed Asymmetric Ion Pairing Studies

Contributors

Published in

Publication date

Abstract

Keywords

UNIGE affiliation entities

Citation (ISO format)

Main files (1)

Identifiers

Journal ISSN

Technical informations

Creation

First validation

Update

Status update

Last indexation