Article - 
Limited access to UNIGE
Highlights
More informations
Home
Titles listChiral Boron-Bridged Bisoxazolines: Readily Available Anionic Ligands for Asymmetric Catalysis
Titles listChiral Boron-Bridged Bisoxazolines: Readily Available Anionic Ligands for Asymmetric Catalysis
Scientific Article
unige:6980 
 |
Chiral Boron-Bridged Bisoxazolines: Readily Available Anionic Ligands for Asymmetric Catalysis |
|
| Authors | ||
| Published in | Angewandte Chemie: International Edition. 2005, vol. 44, no. 31, p. 4888-4891 | |
| Abstract | Asymmetric cyclopropanation and monobenzoylation reactions of meso diols employing borabox catalysts 1 (M=Cu) result in high enantioselectivities. The borabox ligands are anionic analogues of the bisoxazolines 2 and are readily prepared by lithiation of oxazolines and subsequent trapping with boron halides. The considerable potential of borabox ligands in asymmetric catalysis is shown. | |
| Keywords | acylation — asymmetric catalysis — copper — diazo compounds — N ligands | |
| Identifiers | ||
| Full text | ||
| Citation (ISO format) | MAZET, Clement, KÖHLER, Valentin, PFALTZ, Andreas. Chiral Boron-Bridged Bisoxazolines: Readily Available Anionic Ligands for Asymmetric Catalysis. In: Angewandte Chemie: International Edition, 2005, vol. 44, n° 31, p. 4888-4891. https://archive-ouverte.unige.ch/unige:6980 |
192 hits 
39 downloads 
Contact an author
Update